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Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide

Crossley, Ian R; Hill, Anthony; Willis, Anthony

Description

The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].

dc.contributor.authorCrossley, Ian R
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-08T22:18:40Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/31449
dc.description.abstractThe reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chemical bonds; Complexation; Ligands; Organometallics; Synthesis (chemical); Carbon monosulfide; Ligand activating function; Metathesis; Phosphaboration; Boron compounds
dc.titleMetallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume26
dc.date.issued2007
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationu4217927xPUB83
local.type.statusPublished Version
local.contributor.affiliationCrossley, Ian R, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue16
local.bibliographicCitation.startpage3891
local.bibliographicCitation.lastpage3895
local.identifier.doi10.1021/om700433q
dc.date.updated2015-12-08T08:18:20Z
local.identifier.scopusID2-s2.0-34547797363
CollectionsANU Research Publications

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