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A homoleptic hydrotris(methimazolyl)borate complex of titanium

Hill, Anthony; Smith, Matthew

Description

The reaction of [Ti2(-Cl)2(thf)2(η- C8H8)2] with Na[HB(mt)3] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)3} 2][TiCl4(thf)2], the cation of which features homoleptic TiIIIS6 coordination.

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/31240
Source: Dalton Transactions
DOI: 10.1039/b707265a

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