Evidence from FTIR Difference Spectroscopy of an Extensive Network of Hydrogen Bonds near the Oxygen-Evolving Mn4Ca Cluster of Photosystem II Involving D1-Glu65, D2-Glu312, and D1-Glu329
Analyses of the refined X-ray crystallographic structures of photosystem II (PSII) at 2.9-3.5 Å have revealed the presence of possible channels for the removal of protons from the catalytic Mn4Ca cluster during the water-splitting reaction. As an initial
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