Bis(acetylacetonato)ruthenium(II) complexes containing alkynyldiphenylphosphines. Formation and redox behavior of [Ru(acac) 2 (Ph 2 PC≡CR) 2 ] (R = H, Me, Ph) complexes and the binuclear complex cis -[{Ru(acac) 2 } 2 (μ-Ph 2 PC≡CPPh 2 )} 2 ]
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Bennett, Martin; Byrnes, Matthew; Willis, Anthony
Description
Two equivalents of Ph2PCCR (R = H, Me, Ph) react with thf solutions of cis-[Ru(acac)2(η2-alkene)2] (acac = acetylacetonato; alkene = C2H4, 1; C 8H14, 2) at room temperature to yield the orange, air-stable compounds trans-[Ru(acac)2(Ph2PCCR) 2] (R = H, tr
Collections | ANU Research Publications |
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Date published: | 2007 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/28598 |
Source: | Dalton Transactions |
DOI: | 10.1039/b618365d |
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