Skip navigation
Skip navigation
A change is coming. Click to see a sneak peek of the new Open Research Repository.

Arsolyl-supported intermetallic dative bonding

Open Access

Download (698.78 kB)

link to publisher version

  • Altmetric Citations

Kirk, Ryan; Hill, Anthony

Description

The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

dc.contributor.authorKirk, Ryan
dc.contributor.authorHill, Anthony
dc.date.accessioned2023-01-03T05:31:19Z
dc.date.available2023-01-03T05:31:19Z
dc.identifier.issn2041-6520
dc.identifier.urihttp://hdl.handle.net/1885/282556
dc.description.abstractThe first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP190100723 and DP200101222) for funding
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© 2022 The Author(s). Published by the Royal Society of Chemistry
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.sourceChemical science
dc.titleArsolyl-supported intermetallic dative bonding
dc.typeJournal article
local.identifier.citationvolume13
dc.date.issued2022-06-15
local.publisher.urlhttps://pubs.rsc.org/
local.type.statusPublished Version
local.contributor.affiliationHill, A., College of Science, The Australian National University
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723
dc.relationhttp://purl.org/au-research/grants/arc/DP200101222
local.bibliographicCitation.issue23
local.bibliographicCitation.startpage6830
local.bibliographicCitation.lastpage6835
local.identifier.doi10.1039/d2sc01200f
dcterms.accessRightsOpen Access
dc.provenanceThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
dc.rights.licenseCreative Commons Attribution 3.0 Unported Licence
CollectionsANU Research Publications

Download

File Description SizeFormat Image
d2sc01200f.pdf698.78 kBAdobe PDFThumbnail
Show simple item record


This item is licensed under a Creative Commons License Creative Commons

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator