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Arsolyl-supported intermetallic dative bonding

Kirk, Ryan; Hill, Anthony


The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

CollectionsANU Research Publications
Date published: 2022-06-15
Type: Journal article
Source: Chemical science
DOI: 10.1039/d2sc01200f
Access Rights: Open Access


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