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Thiocarbonylphosphorane and arsorane ligands

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Burt, Liam; Hill, Anthony; Jones, Stephanie

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Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.

dc.contributor.authorBurt, Liam
dc.contributor.authorHill, Anthony
dc.contributor.authorJones, Stephanie
dc.date.accessioned2023-01-03T05:28:03Z
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/282555
dc.description.abstractIndependently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP190100723 and DP200101222) for funding.
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© 2022 Royal Society of Chemistry
dc.sourceChemical communications
dc.subjectcrystallography, x-ray
dc.subjectligands
dc.subjectmodels, molecular
dc.subjectsulfur
dc.subjectborates
dc.subjectsalts
dc.titleThiocarbonylphosphorane and arsorane ligands
dc.typeJournal article
local.identifier.citationvolume58
dc.date.issued2022-10-04
local.publisher.urlhttps://pubs.rsc.org/
local.type.statusAccepted Version
local.contributor.affiliationBert, L., College of Science, The Australian National University
local.contributor.affiliationHill, A., College of Science, The Australian National University
local.description.embargo2023-10-04
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723
dc.relationhttp://purl.org/au-research/grants/arc/DP200101222
local.identifier.essn1364-548X
local.bibliographicCitation.issue79
local.bibliographicCitation.startpage11091
local.bibliographicCitation.lastpage11094
local.identifier.doi10.1039/d2cc03747e
dcterms.accessRightsOpen Access
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18003..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 03/01/2023).
CollectionsANU Research Publications

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