Heterobimetallic μ2-halocarbyne complexes
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Burt, Liam; Dewhurst, Rian; Hill, Anthony; Yuze Kong, Richard; Nahon, Emily; Onn, Chee Sheng
Description
The halocarbyne complexes [M(CX)(CO)2(Tp*)] (M = Mo, W; X = Cl, Br; Tp* = hydrotris(dimethylpyrazolyl)borate) react with [AuCl(SMe2)], [Pt(η2-H2CCH2)(PPh3)2] or [Pt(η2-nbe)3] (nbe = norbornene) to furnish rare examples of μ2-halocarbyne complexes [MAu(μ2-CX)Cl(CO)2(Tp*)], [MPt(μ2-CCl)(CO)2(PPh3)2(Tp*)] and [W2Pt(μ2-CCl)2(CO)4(Tp*)2]. The complex [WPt(μ2-CCl)(CO)2(PPh3)2(Tp*)] spontaneously rearranges to the μ2-carbido complex [WPt(μ2-C)Cl(CO)2(PPh3)2(Tp*)] during silica-gel chromatography....[Show more]
Collections | ANU Research Publications |
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Date published: | 2022-08-16 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/282554 |
Source: | Dalton transactions |
DOI: | 10.1039/d2dt01558g |
Access Rights: | Open Access |
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10.1039_D2DT01558G Heterobimetallic Halocarbynes.pdf | 6.16 MB | Adobe PDF |
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