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Organometallic flow chemistry: solvento complexes

Frogley, Benjamin; Hill, Anthony; Onagi, Hideki; Watson, Lachlan


Photolysis under optimised flow conditions of metal carbonyls [{Ln}M(CO)x] [{Ln}M(CO)x = Cr(CO)6, Mo(CO)6, W(CO)6, Mn(CO)3(η-C5H4Me), Re(CO)3(η-C5H5)] in tetrahydrofuran (THF) conveniently affords the synthetically versatile and labile solvento complexes [{Ln}M(CO)x-1(THF)], thereby obviating many of the caveats associated with photochemical syntheses using either 'batch' or falling film techniques. Conversions were optimised and yields assayed by a combination of in situ infrared spectroscopy...[Show more]

CollectionsANU Research Publications
Date published: 2022-11-21
Type: Journal article
Source: Dalton transactions
DOI: 10.1039/d2dt02583c
Access Rights: Open Access


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