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Tetrel and pnictogen functionalised propargylidynes

Manzano, Richard; Hill, Anthony; Georgelin, Rosemary

Description

The reaction of [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CSiMe3)(CO)2(Tp*)] (Tp* = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CAg)-(CO)2(Tp*)][AgNO3]}n while [Hg{C[triple bond, length as m-dash]CC[triple bond, length as m-dash]W(CO)2(Tp*)}2] with nBuLi affords [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CLi)(CO)2(Tp*)]. These anhydrous reagents allow the installation of...[Show more]

CollectionsANU Research Publications
Date published: 2020
Type: Journal article
URI: http://hdl.handle.net/1885/282551
Source: Chemical Communications
DOI: 10.1039/d0cc06196d

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