Tuning out vibrational levels in molecular electron energy-loss spectra
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Heays, Alan; Lewis, Brenton; Gibson, Stephen; Malone, C.P.; Johnson, P V; Kanik, Isik; Khakoo, M.A.
Description
The phenomenon whereby features associated with certain vibrational levels in molecular states of mixed electronic character disappear under specific scattering conditions in electron energy-loss spectra is investigated. In particular, using a combination of experimental measurements and coupled-channel calculations, anomalous vibrational intensities in the mixed valence-Rydberg 1Π u←X1Σg+ transition of N 2 are explained. A single parameter, i.e., the ratio of the generalized electronic...[Show more]
Collections | ANU Research Publications |
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Date published: | 2012 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/28203 |
Source: | Physical Review A: Atomic, Molecular and Optical Physics |
DOI: | 10.1103/PhysRevA.85.012705 |
Access Rights: | Open Access |
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01_Heays_Tuning_out_vibrational_levels_2012.pdf | 480.27 kB | Adobe PDF |
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