Tuning out vibrational levels in molecular electron energy-loss spectra
The phenomenon whereby features associated with certain vibrational levels in molecular states of mixed electronic character disappear under specific scattering conditions in electron energy-loss spectra is investigated. In particular, using a combination of experimental measurements and coupled-channel calculations, anomalous vibrational intensities in the mixed valence-Rydberg 1Π u←X1Σg+ transition of N 2 are explained. A single parameter, i.e., the ratio of the generalized electronic...[Show more]
|Collections||ANU Research Publications|
|Source:||Physical Review A: Atomic, Molecular and Optical Physics|
|Access Rights:||Open Access|
|01_Heays_Tuning_out_vibrational_levels_2012.pdf||480.27 kB||Adobe PDF|
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