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Metallosupramolecular Architectures of Ambivergent Bis(Amino Acid) Biphenyldiimides

Boer, Stephanie; Turner, David


The metallosupramolecular chemistry of two enantiopure dicarboxylate ligands has been explored for their potential to form discrete or polymeric interlocked motifs. Consequently, both discrete and polymeric supramolecular complexes have been synthesised, yielding M2L2 metallomacrocycles (1 and 2), a heteroleptic M2L3 metallomacrobicycle (3), a non‐interpenetrated coordination polymer (4), and highly unusual chiral M8L8 squares (5 and 6). There appears to be a preference for the ligands to form...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Chemistry - An Asian Journal
DOI: 10.1002/asia.201900665


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