Design of ketone derivatives as highly efficient photoinitiators for free radical and cationic photopolymerizations and application in 3D printing of composites
Xu, Yangyang; Ding, Zhao-Fu; Zhu, Haibin; Graff, Bernadette; Knopf, Stephan; Xiao, Pu; Dumur, Frederic; Lalevee, J
Herein, thirteen ketone derivatives composed of different cyclohexanone cores and peripheral moieties are designed, among which 10 ketones have never been synthesized before. These ketones are proposed as high-performance photoinitiators for both free radical polymerizations and cationic polymerizations under soft conditions (visible LED@405 nm irradiation at room temperature). In combination with an amine and an iodonium salt (Iod), these ketones could be used in three−component...[Show more]
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|Source:||Journal of Polymer Science|
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