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Rational design of photo-cleavable alkoxyamines for polymerization and synthesis

Hill, Nicholas; Coote, Michelle


Theoretical calculations have been performed in order to investigate the impact of different substitution patterns on predicted photoreactivity of alkoxyamines fused to an anthraquinone chromophore. Amino and hydroxy groups (similar to those which have been previously synthesized) are introduced and their effect on excited state energies and charge transfer is assessed. Analogous to formally oxidized alkoxyamines, the charge-separated nNp* state can undergo mesolytic cleavage or bimolecular or...[Show more]

CollectionsANU Research Publications
Date published: 2020
Type: Journal article
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/d0cp02924f
Access Rights: Open Access


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