Solid Nanoporosity Governs Catalytic CO2 and N2 Reduction
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Naseem, Fizza; Lu, Peilong; Zeng, Jianping; Lu, Ziyang; Ng, Yun Hau; Zhao, Haitao; Du, Yaping; Yin, Zongyou
Description
Global demand for green and clean energy is increasing day by day owing to ongoing developments by the human race that are changing the face of the earth at a rate faster than ever. Exploring alternative sources of energy to replace fossil fuel consumption has become even more vital to control the growing concentration of CO2, and reduction of CO2 into CO or other useful hydrocarbons (e.g., C1 and C>2 products), as well as reduction of N2 into ammonia, can greatly help in this regard. Various...[Show more]
dc.contributor.author | Naseem, Fizza | |
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dc.contributor.author | Lu, Peilong | |
dc.contributor.author | Zeng, Jianping | |
dc.contributor.author | Lu, Ziyang | |
dc.contributor.author | Ng, Yun Hau | |
dc.contributor.author | Zhao, Haitao | |
dc.contributor.author | Du, Yaping | |
dc.contributor.author | Yin, Zongyou | |
dc.date.accessioned | 2022-07-21T04:55:41Z | |
dc.identifier.issn | 1936-0851 | |
dc.identifier.uri | http://hdl.handle.net/1885/269855 | |
dc.description.abstract | Global demand for green and clean energy is increasing day by day owing to ongoing developments by the human race that are changing the face of the earth at a rate faster than ever. Exploring alternative sources of energy to replace fossil fuel consumption has become even more vital to control the growing concentration of CO2, and reduction of CO2 into CO or other useful hydrocarbons (e.g., C1 and C>2 products), as well as reduction of N2 into ammonia, can greatly help in this regard. Various materials have been developed for the reduction of CO2 and N2. The introduction of pores in these materials by porosity engineering has been demonstrated to be highly effective in increasing the efficiency of the involved redox reactions, over 40% increment for CO2 reduction to date, by providing an increased number of exposed facets, kinks, edges, and catalytically active sites of catalysts. By shaping the surface porous structure, the selectivity of the redox reaction can also be enhanced. In order to better understand this area benefiting rational design for future solutions, this review systematically summarizes and constructively discusses the porosity engineering in catalytic materials, including various synthesis methods, characterization of porous materials, and the effects of porosity on performance of CO2 reduction and N2 reduction. | |
dc.description.sponsorship | F.N., P.L., J.Z., Z.L., and Z.Y. received funding from the Australian Research Council (DP190100295, LE190100014), the ANU Futures Scheme (Q4601024), and ANU Global Research Partnership Scheme (R468504649). Y.D. received funding from National Natural Science Foundation of China (21971117, 21522106), Functional Research Funds for the Central Universities, Nankai University (63186005), Tianjin Key Lab for Rare Earth Materials and Applications (ZB19500202), and 111 Project (No. B18030) from China. F.N. received funding from International Research Support Initiative Program (No. 8405) HEC, Pakistan. | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_AU | |
dc.publisher | American Chemical Society | |
dc.rights | © 2020 American Chemical Society | |
dc.source | ACS Nano | |
dc.subject | nanoporosity | |
dc.subject | pore size | |
dc.subject | surface area | |
dc.subject | catalysis | |
dc.subject | CO2 reduction | |
dc.subject | N2 reduction | |
dc.subject | 2D materials | |
dc.subject | energy conversion | |
dc.title | Solid Nanoporosity Governs Catalytic CO2 and N2 Reduction | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 14 | |
dcterms.dateAccepted | 2020-06-15 | |
dc.date.issued | 2020-06-15 | |
local.identifier.absfor | 340601 - Catalysis and mechanisms of reactions | |
local.identifier.absfor | 340300 - Macromolecular and materials chemistry | |
local.identifier.ariespublication | a383154xPUB14430 | |
local.publisher.url | https://pubs.acs.org/ | |
local.type.status | Published Version | |
local.contributor.affiliation | Naseem, Fizza, College of Science, ANU | |
local.contributor.affiliation | Lu, Peilong, College of Science, ANU | |
local.contributor.affiliation | Zeng, Jianping, College of Science, ANU | |
local.contributor.affiliation | Lu, Ziyang, College of Science, ANU | |
local.contributor.affiliation | Ng, Yun Hau, City University of Hong Kong | |
local.contributor.affiliation | Zhao, Haitao, Massachusetts Institute of Technology | |
local.contributor.affiliation | Du, Yaping, Nankai University | |
local.contributor.affiliation | Yin, Zongyou, College of Science, ANU | |
local.description.embargo | 2099-12-31 | |
dc.relation | http://purl.org/au-research/grants/arc/DP190100295 | |
dc.relation | http://purl.org/au-research/grants/arc/LE190100014 | |
local.bibliographicCitation.issue | 7 | |
local.bibliographicCitation.startpage | 7734 | |
local.bibliographicCitation.lastpage | 7759 | |
local.identifier.doi | 10.1021/acsnano.0c02731 | |
dc.date.updated | 2024-03-03T07:16:21Z | |
local.identifier.thomsonID | WOS:000557762800008 | |
Collections | ANU Research Publications |
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