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Copper(I) Complex [Cu(ca 2 dapte)(NCS)] with the Flexible N 2 S 2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

Morshedi, Mahbod; Amirnasr, Mehdi; Triki, Smail; Khalaji, Aliakbar Dehno

Description

New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca2dapte [Cu(ca2dapte)(NCS)], [ca 2dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio) ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca2dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/25983
Source: Journal of Chemical Crystallography
DOI: 10.1007/s10870-010-9833-4

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