Copper(I) Complex [Cu(ca 2 dapte)(NCS)] with the Flexible N 2 S 2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure
New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca2dapte [Cu(ca2dapte)(NCS)], [ca 2dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio) ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca2dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to...[Show more]
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|Source:||Journal of Chemical Crystallography|
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