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Periodic trends in metal-metal interactions in face-shared [M 2 Cl 9 ] z- systems

Cavigliasso, German; Lovell, Timothy; Stranger, Robert

Description

The periodic trends in metal-metal interactions in even-electron and mixed-valence [M2Cl9]z- face-shared systems, involving transition metals in Groups 4 to 8 and electronic configurations ranging from d1d1 through to d5d5 and from d1d2 through to d4d5, have been investigated by calculating metal-metal bonding and spin polarization (exchange) effects using density functional theory. These two terms are in opposition to one another and their relative difference determines the extent to which the...[Show more]

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/25510
Source: Dalton Transactions
DOI: 10.1039/b512393c

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