Organometallic complexes for nonlinear optics.66. Synthesis and quadratic nonlinear optical studies of trans-[Ru{C=C{2,5-C4H2S-( E )-CH=CH}n-2,5-C4H2S(NO2 )}Cl(dppe)2](n1/40-2)
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Qui, Siya; Morshedi, Mahbod; Kodikara, Mahesh S; Du, Jun; Coene, Yovan; Zhang, Chi; Clays, Koen Jan; Humphrey, Mark
Description
Oligo(2,5-thienylenevinylene)s (OTVs) end-functionalized with a ligated ruthenium alkynyl unit as adonor and a nitro as acceptor, namelytrans-[Ru{C^C-2,5-C4H2S(NO2)}Cl(dppe)2](Ru1T),trans-[Ru{C^C-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S(NO2)}Cl(dppe)2](Ru2T), andtrans-[Ru{C^C-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S-(E)-CH]CH-2,5-C4H2S(NO2)}Cl(dppe)2](Ru3T), have been synthesized, their elec-trochemical properties have been assessed by cyclic voltammetry (CV), their linear optical and quadratic nonlinear optical...[Show more]
Collections | ANU Research Publications |
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Date published: | 2020-07-15 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/251640 |
Source: | Journal of Organometallic Chemistry |
DOI: | 10.1016/j.jorganchem.2020.121306 |
Access Rights: | Open Access |
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