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Tuneable reversible redox of cobalt(iii) carbazole complexes

Bennington, Michael S.; Feltham, Humphrey L.; Buxton, Zoë J.; White, Nicholas; Brooker, Sally


Four tridentate carbazole-based ligands, HLtBu/H {3,6-di(tert-butyl)-1,8-bis[5-(3-benzyl-1,2,3-triazole)]-9H-carbazole}, HLtBu/tBu {3,6-di(tert-butyl)-1,8-bis[5-(3-(4-tert-butyl)benzyl-1,2,3-triazole)]-9H-carbazole}, HLH/H {1,8-bis[5-(3-benzyl-1,2,3-triazole)]-9H-carbazole} and HLH/tBu {1,8-bis[5-(3-(4-tert-butyl)benzyl-1,2,3-triazole)]-9H-carbazole}, were prepared and complexed with cobalt(ii) tetrafluoroborate. In situ air oxidation resulted in cobalt(iii) complexes 1-4 with the general...[Show more]

CollectionsANU Research Publications
Date published: 2017
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/C7DT00295E


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