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Spiroacetal Biosynthesis: (±)-1,7-Dioxaspiro[5.5]undecane in Bactrocera cacuminata and Bactrocera oleae (Olive Fruit Fly)

Schwartz, Brett; McErlean, Christopher S P; Fletcher, Mary T; Mazomenos, Basilis E; Konstantopoulou, Maria A; Kitching, William; De Voss, James Joseph


A biosynthetic scheme rationalizing the formation of (±)-1,7- dioxaspiro[5.5]undecane (5) in the fruit fly species Bactrocera cacuminata and Bactrocera oleae (olive fruit fly) is presented. Incorporation studies with deuterium-labeled keto aldehyde (10),

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol050143w


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