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Stille/Diels-Alder reaction sequences: diversity-oriented access to novel steroids

Sunnemann, Hans Wolf; Hofmeister, Anja; Magull, Jörg; Banwell, Martin; de Meijere, Armin


An efficient, diversity-oriented approach to novel steroid analogues possessing a C-5β configuration begins with the Stille cross-coupling of enantiomerically pure cycloalkenylstannane trans-2 and enol triflate 3. The resulting diene trans-4 engages in D

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol062878m


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