Chiral dendralenes for rapid access to enantiomerically pure polycycles
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Miller, Natalie; Willis, Anthony; Paddon-Row, Michael; Sherburn, Michael
Description
(Chemical Equation Presented) On a short fuse: Highly stereoselective and atom-efficient domino Diels-Alder/ lactonization/Diels-Alder sequences can be carried out using simple chiral [3]dendralenes to form fused-ring systems. This short and general approach to cross-conjugated systems promotes the rapid assembly of enantiomerically pure polycyclic ring systems common to biologically interesting terpenoids with virtually complete stereocontrol (see scheme).
Collections | ANU Research Publications |
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Date published: | 2007 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/23470 |
Source: | Angewandte Chemie International Edition |
DOI: | 10.1002/anie.200603335 |
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01_Miller_Chiral_dendralenes_for_rapid_2007.pdf | 224.06 kB | Adobe PDF | Request a copy |
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