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The incommensurately modulated NiGe1-xPx, ~0.3≤x≤~0.7, solid solution: The 'missing link' between the NiP and MnP structure types

Larsson, Ann-Kristin; Garcia-Garcia, F Javier; Withers, Raymond

Description

The (3 + 1)-d incommensurately modulated structures of four members of the NiGe1 - x Px solid solution field have been successfully refined from X-ray powder diffraction data (Rw (all) / Rwp = 2.13 / 3.92; 1.52/4.25; 1.27/3.44 and 2.00/4.03 for x = 0.4, 0.5, 0.6 and 0.7, respectively). The 4-d superspace group symmetry is Amam (0 0 γ) s 0 0 (Z = 4; a = 5.0468 (2), 5.0188(2), 4.9796(2) and 4.9651 (1) Å; b = 6.0636 (3), 6.0576(2), 6.0183(2) and 6.0031 (1) Å; c = 3.4877 (2), 3.4812(2), 3.4593(1)...[Show more]

CollectionsANU Research Publications
Date published: 2007
Type: Journal article
URI: http://hdl.handle.net/1885/23311
Source: Journal of Solid State Chemistry
DOI: 10.1016/j.jssc.2007.01.006

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