Application of the aza-Diels-Alder reaction in the synthesis of natural products
The Diels–Alder reaction that involves a nitrogen atom in the diene or dienophile is termed the aza-Diels–Alder reaction. As well as the powerful all-carbon Diels–Alder reaction, the aza-Diels–Alder reaction has also played an important role in the total synthesis of natural products. Herein, we review various natural products using an aza-Diels–Alder reaction as a key step to their total synthesis, and divide the syntheses into inter- and intra-molecular aza-Diels–Alder reactions and a...[Show more]
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|Source:||Organic and Biomolecular Chemistry|
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