Cluster chemistry in the solid state: Structured diffuse scattering, oxide/fluoride ordering and polar behaviour in transition metal oxyfluorides
Oxide/fluoride ordering in three families of 'disordered' transition metal oxyfluoride compounds is carefully investigated and used to obtain insight into why the constituent inherently acentric octahedral units do not usually order in a long range ordered polar sense. Observed highly structured diffuse intensity distributions are used in each case to analyze the local crystal chemistry and orientational ordering rules governing the way in which the dipole moments from the individual polar...[Show more]
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