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Supramolecular frameworks based on 5,10,15,20-tetra(4-carboxyphenyl)porphyrins

Morshedi, Mahbod; Ward, Jas; Kruger, Paul E.; White, Nicholas


We have investigated the hydrogen bond-driven assembly of nickel and freebase tetra(carboxyphenyl) and tetra(carboxylatophenyl) porphyrins. When the tetracarboxylates were crystallized with bis(amidinium) species, their crystal structures contained a range of hydrogen bond geometries, and we did not obtain well-ordered networks. Use of a tetrahedral tetra(amidinium) building block yielded a 3D framework material with a PtS topology, which contains only a “paired” hydrogen bonding arrangement....[Show more]

CollectionsANU Research Publications
Date published: 2017-12-15
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/C7DT04162D
Access Rights: Open Access


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