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Observation of a Tungsten Alkane σ-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies

Young, Rowan; Lawes, Douglas J; Hill, Anthony; Ball, Graham


The alkane σ-complex (HEB)W(CO)2(pentane) (HEB = η6-hexaethylbenzene) is produced from the UV photolysis of (HEB)W(CO)3 in alkane solvents at low temperature. IR and1H and13C NMR spectroscopic data are reported, representing the first NMR data for a gou

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja300281s


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