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Theoretical Study of the Oxidation Mechanism of Hematoxylin in Aqueous Solution

Namazian, Mansoor; Zare, Hamid; Coote, Michelle

Description

The oxidation of the two catechol rings A and B in the chemical structure of hematoxylin in aqueous solution has been studied theoretically in order to identify the mechanism of oxidation. In a recent experimental study, the oxidation mechanism of hematoxylin was designated an ErCiEr process in which an irreversible chemical reaction (Ci) followed the reversible chemical electrochemical oxidation (Er) of the catechol unit connected to the six-membered ring of the molecule (ring A). The...[Show more]

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/21995
Source: Australian Journal of Chemistry
DOI: 10.1071/CH12019

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