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Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to cis-[(dppe)M(?C-2-C6F4PPh2)2] (M = Ni, Pd, and Pt)

Gericke, Robert; Bennett, Martin; Priver, Steven H; Bhargava, Suresh Kumar


The reactivity of [(dppe)M(κC-2-C6F4PPh2)2] (M = Ni (1Ni), Pd (1Pd), and Pt (1Pt); dppe = 1,2-bis(diphenylphosphino)ethane)) toward monovalent coinage metal ions (M′ = Cu, Ag, and Au) has been investigated. Two main isomers [(dppe)M(κC-2-C6F4PPh2)(μ-2-C6F4PPh2)M′Cl] (2PdAg, 2PdAu, 2PtCu, 2PtAg, and 2PtAu) and [(dppe)M(μ-2-C6F4PPh2)2M′Cl] (3PdCu, 3PdAg, and 3PtCu) could be detected. Quantum chemical calculations underpin the enhanced thermodynamic stability of...[Show more]

CollectionsANU Research Publications
Date published: 2017
Type: Journal article
Source: Organometallics
DOI: 10.1021/acs.organomet.7b00145


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