Goossens, Darren; Henderson, Lachlan; Trevena, Shawn; Hudspeth, Jessica; Avdeev, Maxim; Hester, James
LaCa2Fe3O8 (A3B3O8) is an example of a layered structure in that it consists of pairs of octahedral, perovskite-like layers alternating with a single tetrahedral layer. This work explores the doping of non-magnetic group 13 elements, M=Al, Ga and In, onto the B-site of LaCa2Fe3-xMxO8 as a function of x. The structural and magnetic effects are examined using a combination of neutron and X-ray diffraction. Solubility limits are established. It is found that for M=Ga the solubility limit occurs...[Show more]
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