The crystal and magnetic structures of LaCa 2 Fe 3-x M x O 8 (M = Al, Ga, In)
LaCa2Fe3O8 (A3B3O8) is an example of a layered structure in that it consists of pairs of octahedral, perovskite-like layers alternating with a single tetrahedral layer. This work explores the doping of non-magnetic group 13 elements, M=Al, Ga and In, onto the B-site of LaCa2Fe3-xMxO8 as a function of x. The structural and magnetic effects are examined using a combination of neutron and X-ray diffraction. Solubility limits are established. It is found that for M=Ga the solubility limit occurs...[Show more]
|Collections||ANU Research Publications|
|Source:||Journal of Solid State Chemistry|
|01_Goossens_The_crystal_and_magnetic_2012.pdf||813.67 kB||Adobe PDF||Request a copy|
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.