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Metal coordination to a dimetallaoctatetrayne

Delaney, Andie; Frogley, Benjamin; Hill, Anthony

Description

The reactions of the ditungstaoctatetrayne [(Tp*)(CO)2W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash])W(CO)2(Tp*)] with several metal complexes have been investigated. Addition of [Co2(CO)8] occurs across the internal C[triple bond, length as m-dash]C bonds, whereas [AuCl(SMe2)] initially delivers 'AuCl' across the W[triple bond, length as m-dash]C carbyne bonds before undergoing further reaction to oxidise the...[Show more]

CollectionsANU Research Publications
Date published: 2019-09-28
Type: Journal article
URI: http://hdl.handle.net/1885/217239
Source: Dalton transactions
DOI: 10.1039/c9dt03041g
Access Rights: Open Access

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