Skip navigation
Skip navigation

Heterobimetallic μ2-carbido complexes of platinum and tungsten

Burt, Liam; Hill, Anthony

Description

The tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp*)] (Tp* = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp*)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp*)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp*)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp*)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp*)(Tp*)],...[Show more]

dc.contributor.authorBurt, Liam
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-12-13T23:44:43Z
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/217039
dc.description.abstractThe tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp*)] (Tp* = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp*)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp*)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp*)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp*)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp*)(Tp*)], [WPt(μ-C)(CO)2(PPh3)(Tp*)2] and [WPt(μ-C)(bipy)(CO)2(PPh3)(Bm)(Tp*)], most of which have been structurally charcaterised.
dc.description.sponsorshipDP170102695 and DP190100723
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© Royal Society of Chemistry 2020
dc.sourceDalton transactions
dc.titleHeterobimetallic μ2-carbido complexes of platinum and tungsten
dc.typeJournal article
local.identifier.citationvolume49
dc.date.issued2020-06-23
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/DT
local.type.statusAccepted Version
local.contributor.affiliationResearch School of Chemistry, The Australian National University
local.contributor.affiliationHill, A., Research School of Chemistry, The Australian National University
local.description.embargo2021-06-23
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723
local.identifier.essn1477-9234
local.bibliographicCitation.issue24
local.bibliographicCitation.startpage8143
local.bibliographicCitation.lastpage8161
local.identifier.doi10.1039/d0dt01617a
dcterms.accessRightsOpen Access
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).
CollectionsANU Research Publications

Download

File Description SizeFormat Image
10.1039_d0dt01617a.pdf5.58 MBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator