Heterobimetallic μ2-carbido complexes of platinum and tungsten
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The tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp*)] (Tp* = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp*)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp*)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp*)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp*)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp*)(Tp*)],...[Show more]
dc.contributor.author | Burt, Liam![]() | |
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dc.contributor.author | Hill, Anthony![]() | |
dc.date.accessioned | 2020-12-13T23:44:43Z | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/1885/217039 | |
dc.description.abstract | The tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp*)] (Tp* = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp*)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp*)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp*)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp*)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp*)(Tp*)], [WPt(μ-C)(CO)2(PPh3)(Tp*)2] and [WPt(μ-C)(bipy)(CO)2(PPh3)(Bm)(Tp*)], most of which have been structurally charcaterised. | |
dc.description.sponsorship | DP170102695 and DP190100723 | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_AU | |
dc.publisher | Royal Society of Chemistry | |
dc.rights | © Royal Society of Chemistry 2020 | |
dc.source | Dalton transactions | |
dc.title | Heterobimetallic μ2-carbido complexes of platinum and tungsten | |
dc.type | Journal article | |
local.identifier.citationvolume | 49 | |
dc.date.issued | 2020-06-23 | |
local.identifier.ariespublication | a383154xPUB14156 | |
local.publisher.url | http://pubs.rsc.org/en/Journals/JournalIssues/DT | |
local.type.status | Accepted Version | |
local.contributor.affiliation | Research School of Chemistry, The Australian National University | |
local.contributor.affiliation | Hill, A., Research School of Chemistry, The Australian National University | |
dc.relation | http://purl.org/au-research/grants/arc/DP170102695 | |
dc.relation | http://purl.org/au-research/grants/arc/DP190100723 | |
local.identifier.essn | 1477-9234 | |
local.bibliographicCitation.issue | 24 | |
local.bibliographicCitation.startpage | 8143 | |
local.bibliographicCitation.lastpage | 8161 | |
local.identifier.doi | 10.1039/d0dt01617a | |
dcterms.accessRights | Open Access | |
dc.provenance | https://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020). | |
Collections | ANU Research Publications |
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