Heterobimetallic μ2-carbido complexes of platinum and tungsten
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Description
The tungsten-platinum μ-carbido complex [WPt(μ-C)Br(CO)2(PPh3)2(Tp*)] (Tp* = hydrotris(dimethylpyrazol-1-yl)borate) undergoes facile substitution of both bromide and phosphine ligands to afford a diverse library of μ-carbido complexes that includes [WPt(μ-C)Br(CO)2(dppe)(Tp*)], [WPt(μ-C)(NCMe)(CO)2(PPh3)2(Tp*)]OTf, [WPt(μ-C)(S2CNEt2)(CO)2(PPh3)(Tp*)], [WPt(μ-C)(bipy)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(phen)(CO)2(PPh3)(Tp*)]PF6, [WPt(μ-C)(terpy)(CO)2(Tp*)]PF6, [WPt(μ-C)(CO)2(PPh3)(Bp*)(Tp*)],...[Show more]
Collections | ANU Research Publications |
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Date published: | 2020-06-23 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/217039 |
Source: | Dalton transactions |
DOI: | 10.1039/d0dt01617a |
Access Rights: | Open Access |
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10.1039_d0dt01617a.pdf | 5.58 MB | Adobe PDF |
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