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Metal coordination of phosphoniocarbynes

Onn, Chee Sheng; Hill, Anthony; Olding, Angus

Description

Heterobi- and tetrametallic phosphoniocarbyne bridged complexes [WAu(μ-CPMe2Ph)Cl(CO)2(Tp*)]+ (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate), [W2Cu2(μ-CPMe2Ph)2(μ-Cl)2(CO)4(Tp*)2]2+ and [WPt(μ-CPMe2Ph)(COD)(CO)2(Tp*)]+ (COD = 1,5-cyclo-octadiene) arise from the reactions of the mononuclear terminal phosphoniocarbyne [W([triple bond, length as m-dash]CPMe2Ph)(CO)2(Tp*)]PF6 with [AuCl(THT)] (THT = tetrahydrothiophene), [CuCl(SMe2)] and [Pt(nbe)3] (nbe = norbornene) in the presence of COD. The...[Show more]

CollectionsANU Research Publications
Date published: 2020-09-22
Type: Journal article
URI: http://hdl.handle.net/1885/216913
Source: Dalton transactions
DOI: 10.1039/d0dt02737e
Access Rights: Open Access

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