Skip navigation
Skip navigation

Heteroatom functionalised metal-carbon chains

Onn, Chee Sheng

Description

This thesis explores synthesis and reactivity of tungsten complexes featuring carbon chains that connect multiple metal centres with heteroatom incorporated either within or at the termini of such chains. Alkynylselenolatoalkylidynes have a selenium atom that bridges a metal carbyne and an alkynyl motif. This presents many potential reactive sites - tungsten-carbyne, C-Se, alkynyl CC bonds and potentially the alkynyl terminus. The reaction of [W(CBr)(CO)2(Tp*)] (Tp* =...[Show more]

CollectionsOpen Access Theses
Date published: 2021
Type: Thesis (PhD)
URI: http://hdl.handle.net/1885/216221
DOI: 10.25911/AK6H-BW29

Download

File Description SizeFormat Image
Electronic Supporting Information - NMR spectra.pdfSupporting Material37.62 MBAdobe PDFThumbnail
ESI - ESI-MS.zipSupporting Material51.99 MBUnknown
ESI - XRD.zipSupporting Material67.15 MBUnknown
Final thesis - Cheesheng.pdfThesis Material55.05 MBAdobe PDFThumbnail


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator