Heteroatom functionalised metal-carbon chains
This thesis explores synthesis and reactivity of tungsten complexes featuring carbon chains that connect multiple metal centres with heteroatom incorporated either within or at the termini of such chains. Alkynylselenolatoalkylidynes have a selenium atom that bridges a metal carbyne and an alkynyl motif. This presents many potential reactive sites - tungsten-carbyne, C-Se, alkynyl CC bonds and potentially the alkynyl terminus. The reaction of [W(CBr)(CO)2(Tp*)] (Tp* =...[Show more]
|Collections||Open Access Theses|
|Electronic Supporting Information - NMR spectra.pdf||Supporting Material||37.62 MB||Adobe PDF|
|ESI - ESI-MS.zip||Supporting Material||51.99 MB||Unknown|
|ESI - XRD.zip||Supporting Material||67.15 MB||Unknown|
|Final thesis - Cheesheng.pdf||Thesis Material||55.05 MB||Adobe PDF|
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