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Heteroatom functionalised metal-carbon chains

Onn, Chee Sheng


This thesis explores synthesis and reactivity of tungsten complexes featuring carbon chains that connect multiple metal centres with heteroatom incorporated either within or at the termini of such chains. Alkynylselenolatoalkylidynes have a selenium atom that bridges a metal carbyne and an alkynyl motif. This presents many potential reactive sites - tungsten-carbyne, C-Se, alkynyl CC bonds and potentially the alkynyl terminus. The reaction of [W(CBr)(CO)2(Tp*)] (Tp* =...[Show more]

CollectionsOpen Access Theses
Date published: 2021
Type: Thesis (PhD)
DOI: 10.25911/AK6H-BW29


File Description SizeFormat Image
Electronic Supporting Information - NMR spectra.pdfSupporting Material37.62 MBAdobe PDFThumbnail
ESI - ESI-MS.zipSupporting Material51.99 MBUnknown
ESI - XRD.zipSupporting Material67.15 MBUnknown
Final thesis - Cheesheng.pdfThesis Material55.05 MBAdobe PDFThumbnail

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