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Enhanced two-photon absorption cross-sections of zinc(II) tetraphenylporphyrins peripherally substituted with d 6 -metal alkynyl complexes

Drouet, Samuel; Merhi, Areej; Grelaud, Guillaume; Cifuentes, Marie; Humphrey, Mark; Matczyszyn, Katarzyna; Samoc, Marek; Toupet, L; Paul-Roth, Christine; Paul, Frederic


The syntheses of new Zn(ii) tetraphenylporphyrin (ZnTPP) derivatives functionalized with electron-rich d6-transition metal alkynyl complexes at their periphery are reported. Z-scan measurements reveal remarkably large effective two-photon absorption (TPA) cross-sections in the visible range for these compounds. This journal is

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: New Journal of Chemistry
DOI: 10.1039/c2nj40589j


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