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K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold

Wu, Chao; Lin, Lin; Jiang, Xingxing; Lin, Zheshuai; Huang, Zhipeng; Humphrey, Mark; Halasyamani, P. Shiv; Zhang, Chi


The discovery of nonlinear optical (NLO) materials for generating coherent mid-infrared (mid-IR) light is critically important in developing laser technologies. However, all of the commercialized mid-IR crystals thus far possess problems that have hindered their application. We report herein a function-directing structural design strategy to afford a new type of mid-IR NLO material, using fluorinated 5d0 -transition metal octahedra to construct a polar noncentrosymmetric material...[Show more]

CollectionsANU Research Publications
Date published: 2019-12-04
Type: Journal article
Source: Chemistry of Materials
DOI: 10.1021/acs.chemmater.9b03214
Access Rights: Open Access


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