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Rearrangements in model peptide-type radicals via intramolecular hydrogen-atom transfer

Moran, Damian; Jacob, Rebecca; Wood, Geoffrey P F; Coote, Michelle; Davies, Michael J; O'Hair, Richard A J; Easton, Christopher; Radom, Leo


Intramolecular H-atom transfer in model peptide-type radicals was investigated with high-level quantum-chemistry calculations. Examination of 1,2-, 1,3-, 1,5-, and 1,6[C ↔ N]-H shifts, 1,4- and 1,7[C ↔ C]-H shifts, and 1,4[N ↔ N]-H shifts (Scheme 1)

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Helvetica Chimica Acta
DOI: 10.1002/hlca.200690210


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