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Hydrogen Bonding Guests Direct the Packing of a Small Organic Cage Molecule

Lagones, Thomas; Boer, Stephanie; White, Nicholas

Description

A small organic cage molecule (1) containing six nitrile groups was crystallized in the presence of a number of guests with hydrogen bond donor groups, and from different solvents. In total, eight crystal structures of 1 were obtained, six of which are guest-free and two of which are cocrystals. When the guest was resorcinol or pyrogallol, cocrystals did not form, but the presence of the guests directed formation of new crystalline phases that were not observed when the cage was crystallized...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
URI: http://hdl.handle.net/1885/213220
Source: Crystal Growth and Design
DOI: 10.1021/acs.cgd.9b00565

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