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Tungsten-platinum mu-carbido and mu-methylidyne complexes

Frogley, Benjamin; Hill, Anthony


Reactions of the lithiocarbyne [W]RCLi ([W] = W(CO)2(Tp*); Tp* = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(g-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to l-carbido, l-methylidyne and carbyne-based metalloligand complexes [Pt(CR[W])(terpy)]PF6, [Pt(l-HCR[W])2] and [Pt(CR[W])Cl(phen-CR[W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/c9cc06472a
Access Rights: Open Access


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