Synthons for carbide complex chemistry
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Reinholdt, Anders; Hill, Anthony; Bendix, Jesper
Description
The sterically accessible carbide complex, (Cy3P)Cl3Ru?C-PtCl(py)(2), acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.
Collections | ANU Research Publications |
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Date published: | 2018 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/210658 |
Source: | Chemical Communications |
DOI: | 10.1039/c8cc03596b |
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01_Reinholdt_Synthons_for_carbide_complex_2018.pdf | 2.1 MB | Adobe PDF |
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