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Synthons for carbide complex chemistry

Reinholdt, Anders; Hill, Anthony; Bendix, Jesper

Description

The sterically accessible carbide complex, (Cy3P)Cl3Ru?C-PtCl(py)(2), acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

dc.contributor.authorReinholdt, Anders
dc.contributor.authorHill, Anthony
dc.contributor.authorBendix, Jesper
dc.date.accessioned2020-09-21T00:14:14Z
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/210658
dc.description.abstractThe sterically accessible carbide complex, (Cy3P)Cl3Ru?C-PtCl(py)(2), acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© The Royal Society of Chemistry 2018
dc.sourceChemical Communications
dc.titleSynthons for carbide complex chemistry
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume54
dc.date.issued2018
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationu4485658xPUB1908
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/CC
local.type.statusPublished Version
local.contributor.affiliationReinholdt, Anders, College of Science, ANU
local.contributor.affiliationHill, Anthony, College of Science, ANU
local.contributor.affiliationBendix, Jesper, University of Copenhagen
local.description.embargo2037-12-31
local.bibliographicCitation.issue45
local.bibliographicCitation.startpage5708
local.bibliographicCitation.lastpage5711
local.identifier.doi10.1039/c8cc03596b
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciences
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2020-06-23T00:55:58Z
local.identifier.thomsonID000434314500008
CollectionsANU Research Publications

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