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Synthons for carbide complex chemistry

Reinholdt, Anders; Hill, Anthony; Bendix, Jesper

Description

The sterically accessible carbide complex, (Cy3P)Cl3Ru?C-PtCl(py)(2), acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
URI: http://hdl.handle.net/1885/210658
Source: Chemical Communications
DOI: 10.1039/c8cc03596b

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