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Synthesis and structural characterization of copper(II) complexes with a tetradentate semicarbazone ligand derived from 2,5-hexadione

Vafazadeh, Rasoul; Ehsani, Mahboobeh; Willis, Anthony

Description

Four Cu(II) complexes [CuLH2O](ClO4)2, 1; [CuLCl]Cl.H2O, 2; [CuLBr]2(Cu3Br5), 3; and [CuLH2O](NO3)2, 4; where L=tetradentate semicarbazone ligand, have been synthesized and characterized by elemental analysis, FT-IR and UV–Vis. The structures of compounds 1 and 3 have been determined by single-crystal X-ray difraction analyses. In mononuclear 1, the semicarbazone, L acts as a tetradentate neutral ligand and a water molecule also coordinates to the Cu atom. There are two independent...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
URI: http://hdl.handle.net/1885/210604
Source: Journal of the Iranian Chemical Society
DOI: 10.1007/s13738-019-01721-3

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