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In situ formed [M(CN)(9)] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers

Qian, Jun; Yoshikawa, Hirofumi; Humphrey, Mark; Zhang, Jinfang; Awaga, Kunio; Zhang, Chi


Two interesting nona-cyanometalate-based coordination polymers (CPs) {[μ4-M(CN)9Mn2(dpo)2(DMF)4]·DMF}n (M = W 1, Mo 2) were obtained from the reaction of 2,5-di(4-pyridyl)-1,3,4-oxadiazole (dpo) and (Bu3NH)3[M(CN)8] (M = W, Mo) with Mn(NO3)2·6H2O in DMF. It is noteworthy that the in situ generated [M(CN)9]4− (M = W, Mo), the first nona-cyanometalate-based example of precursor, plays the roles of not only the charge-balancing counter anion but also the molecular building blocks in inducing the...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: CrystEngComm
DOI: 10.1039/c9ce00579j


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