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Syntheses and quadratic nonlinear optical properties of 2,7-fluorenylene- and 1,4-phenylene-functionalized o-carboranes

Jiang, Peng; Wang, Zhaojin; Moxey, Graeme; Morshedi, Mahbod; Barlow, Adam; Wang, Genmiao; Quintana Lopetegui, Cristobal; Zhang, Chi; Cifuentes, Marie; Humphrey, Mark


o-Carboranes C-functionalized by (4-substituted-phen-1-yl)ethynyl-1,4-phenyl groups or (2-substituted-fluoren-7-yl)ethynyl-2,7-fluorenyl groups, in which the pendant functionalization is electron-withdrawing nitro or electron-donating diphenylamino groups, have been synthesized and in many cases structurally characterized. Diphenylamino-containing examples coupled via the two π-delocalizable bridges to the electron-accepting o-carborane unit exhibit the greater quadratic optical...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c9dt02645b
Access Rights: Open Access


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