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Molecular Tectonics: A Node-and-Linker Building Block Approach to a Family of Hydrogen-Bonded Frameworks

Boer, Stephanie; Morshedi, Mahbod; Tarzia, Andrew; Doonan, Christian J.; White, Nicholas


While numerous hydrogen‐bonded organic frameworks (HOFs) have been reported, typically these cannot be prepared predictably or in a modular fashion. In this work, we report a family of nine diamondoid crystalline porous frameworks assembled via hydrogen bonding between poly‐amidinium and poly‐carboxylate tectons. The frameworks are prepared at room temperature in either water or water/alcohol mixtures. Importantly, both the cationic and anionic components can be varied and additional...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Chemistry, A European Journal
DOI: 10.1002/chem.201902117
Access Rights: Open Access


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