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Anion Modulated Structural Variations in Copper(II) Complexes with a Flexidentate Ligand Derived from 2-((2-Aminoethyl)Amino)Ethan-1-ol: Synthesis and Spectroscopic and X-ray Structural Characterization

Vafazadeh, Rasoul; Kazemi-nasab, Abolghasem; Willis, Anthony

Description

Flexidentate ligand, HL has been prepared by the condensation of aminoethylethanolamine (AEEA) with benzoylacetone (bezac). On reaction with copper(II) salts it gives complexes CuLClO4.H2O (1), CuLN3 (2) and [Cu3L3Br]Br2 . H2O (3). All complexes have been characterized by X-ray crystallography. The results show that the hydroxyl group of the flexidentate ligand can coordinate to the Cu(II) center or remain as an uncoordinated group. In (1), the coordination number around the copper(II) ion...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
URI: http://hdl.handle.net/1885/209330
Source: Acta Chimica Slovenica
DOI: 10.17344/acsi.2019.5333
Access Rights: Open Access

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