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A general synthesis of dendralenes

George, Josemon; Ward, Jas; Sherburn, Michael


The first general synthetic approach to substituted [3]- and higher dendralenes is reported. Fifty-one monothrough to penta-substituted dendralenes carrying alkyl-, cycloalkyl-, alkenyl-, alkynyl-, aryl- and heteroaryl-substitutents are accessed, and the first (E)/(Z)-stereoselective syntheses of dendralenes are reported (twenty-eight examples). The approach involves twofold Pd(0)-catalyzed Negishi couplings of 1,1-dibromoalkenes with alkenylzinc reagents, and exploits both substrate- and...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Chemical Science
DOI: 10.1039/c9sc03976g
Access Rights: Open Access


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