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Auxiliary ligand-induced structural diversities of octacyanometalate-based heterobimetallic coordination polymers towards diverse magnetic properties

Qian, Jun; Yoshikawa, Hirofumi; Hu, Jingchun; Humphrey, Mark; Zhang, Jinfang; Awaga, Kunio; Zhang, Chi


Three octacyanometalate-based bimetallic coordination polymers (CPs), {[μ4-MV (CN)8][Co(DMF)4]2(ClO4)}n (M = W CP-1, Mo CP-2) and {[μ4-WIV(CN)8]Co2(azpy)4}n CP-3, were synthesized in the absence (for CPs 1 and 2) or presence (for CP-3) of auxiliary ligand 4,4’-azopyridine (azpy), respectively. CPs 1 and 2 exhibit the same three-dimensional (3D) polymeric cation frameworks with [ClO4] − as the counterions, while CP-3 displays a porous 3D framework in an unusual 2-nodal (4,6)-connected...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c9dt00654k


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